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Beilstein J. Org. Chem. 2010, 6, No. 54, doi:10.3762/bjoc.6.54
Graphical Abstract
Scheme 1: Synthesis of terpyridine-4,4″-dicarboxylic acid (3).
Scheme 2: Synthesis of the terpyridine-4,4″-bisanthrylesters 5a and 5b. The resulting esters 5a and 5b could ...
Scheme 3: Synthesis of the iron(II)-complexes 6a and 6b. The complexes 6a and 6b were obtained in high yields...
Figure 1: UV–vis spectra of 5a before and after irradiation with UV light.
Figure 2: UV–vis spectra of 5b before and after irradiation with UV light.
Figure 3: UV–vis spectra of 6b before and after irradiation with UV light.
Beilstein J. Org. Chem. 2010, 6, No. 53, doi:10.3762/bjoc.6.53
Scheme 1: Synthesis of twofold iodinated bis(benzo[b]thiophenyl)perfluorocyclopentene 4.
Scheme 2: Synthesis of terpyridinyl boronic acids 9a and 9b.
Scheme 3: Synthesis of the bis(terpyridinyl)diarylethenes 10a and 10b.
Scheme 4: Photochromic reaction of the free ligand 10a.
Figure 1: UV–vis-spectra of 10a before (solid), after UV-irradiation (dashed) and after irradiation with vis ...
Scheme 5: Synthesis of the binuclear Ru(II)-complex 12.
Figure 2: UV–vis-spectra of 12 before (solid), after UV-irradiation (dashed) and after irradiation with vis l...
Figure 3: UV–vis-spectra of 12 before (dashed), after UV-irradiation (dotted), the difference (solid) and fre...
Figure 4: UV–vis-spectra of [Fe2+@10a] before (solid), after UV-irradiation (dashed) and after irradiation wi...
Figure 5: UV–vis-spectra of [Zn2+@10a] before (solid), after UV-irradiation (dashed) and after irradiation wi...